Hawking Radiation: A Violation of the Zeroth Law of Thermodynamics Spring 2018 Meeting of the APS New England Section March 16-17, 2018 Suffolk University, Boston, MA Pierre-Marie Robitaille Department of Radiology The Ohio State University Columbus, Ohio 43210 Zeroth Law of Thermodynamics A ↔ B and B ↔ C Then... A↔C But the law also implies that temperature is an intensive property. The temperature of an object cannot depend on extensive properties which in combination do not yield an intensive property. Intensive versus Extensive Properties Intensive Properties Extensive Properties Temperature Mass Pressure Energy Density Enthalpy Concentration Entropy Specific Volume Volume Color Heat Capacity Some properties are neither intensive nor extensive (e.g. radius of a sphere, area of a sphere) Intensive versus Extensive Properties The concept of intensive and extensive properties is so important that Peter Landsberg wanted to establish it as The 4th Law of thermodynamics P.T. Landsberg, Thermodynamics with Quantum Statistical Illustrations, Interscience Publishers, New York, 1961, p. 142. Equations: Intensive versus Extensive Properties “If one side of an equation is extensive (or intensive), then so must be the other side” S.G. Canagaratna Intensive and Extensive Properties: Underused Concepts, J. Chem. Educ., 1992, v. 69, no. 12, 957-963. Ideal Gas Law (P in terms of intensive properties) Entropy of a Black Hole Hawking Temperature